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"Use Edit Log for transactions/masters, and digital signature for invoices/reports with Release 2.1. Download NOW!"
https://help.tallysolutions.com/docs/te9rel66/Tax_India/excise-importer/ei-allocating-custom-duty-items.htm

Allocating Custom Duty to Cost of Items (Excise for Importer)

O n the ledger creation or alteration screen, click F12: Configure and enable the option Allow method of appropriation (used in purchase invoice)? to use the same for cost allocation.